1. Overview

Gas density changes with pressure and temperature, so the use of standardized volumes when referring to quantities of gas is mandatory.

Standardized volumes are commonly used in different types of industries which uses gas as raw material. The volum of gas at actual pressure and temperature must be converted to standardized volumes.

The two common standardized volumes are standard cubic feet (scf) and normal cubic metres (Nm3).

A standard cubic foot of gas corresponds to 1 cubic foot of gas at 60 °F (15.6 °C) and 14.73 PSIA, and a normal cubic metre of gas corresponds to 1 cubic metre at 15°C at 101.325 kPaA. We will see later that It is important to list the temperature and pressure being used as standard, since many standards are used worldwide.

Why we use the standardized flows instead of simple volumetric flow?

We use standardized flows to make calculations easy.

For example, if we are compressing 125 Nm3/min air from 1 bar to 25 bar pressure then the volumetric flow through the compressor will remains same in Nm3/min but this is not the case for the volumetric flow in actual conditions.

The gas being compressible, it is possible to change a volume of the same amount of gas by compressing or changing its temperature.

It becomes very difficult to define of a quantity of gas volume without relating this value with the pressure and temperature when the volume was measured.

Usually is not easy to define the temperature and pressure of a volume of gas, this is why normally we use standardized volumes referred to a define set of temperature and pressure measurements. We call this conditions normalized or standard.

1.1. Acronyms

  • “STP” means “Standard Temperature and Pressure”
  • “NTP” means “Normal Temperature and Pressure”

2. What are the standard temperature and pressure applications?

Standard or normal conditions are used as reference values ​​in thermodynamics of gases. To specify the gas volume, Normal  or Standard temperature and pressure conditions are generally used.

The reason is very simple, the volume of a constant number of moles of gas depends on the measurements of temperature and pressure.

Due to this reason, whenever the quantity of gas is specified in terms of gas volume, it is necessary to define the corresponding temperature and pressure conditions for the volume measurement.

Therefore, we can use the reference temperature and pressure conditions to specify the volume of gas measured under those conditions. Once the volume is calculated, we can convert the calculated amount into an amount of moles or mass of gas.

There are different standards that define different temperature and pressure values. These standards depend on the organization that defines them. In general, the standard pressure is close to atmospheric pressure and the standard temperature is close to the ambient temperature value.

3. Definition

The “gases” by definition are in a gaseous state, under defined pressure and temperature (for example, the nitrogen we breathe). ‘Steam’ and ‘vapors’ are liquids in the conditions described above, although thermodynamically there is no difference between vapor / vapors and gases.

A fundamental difference between liquids and gases is their compressibility (liquids are generally considered incompressible). The compressibility is a property of the matter to which it causes that all the bodies diminish of volume when subjecting them to a pressure or compression determined keeping other parameters constant.

Another important property of gases is that their volume will increase with the increase in temperature, a property of the gas used in hot air balloons.

STP and NTP Flow
STP and NTP Flow

The description of the relationship of these properties is given by the Law of Ideal Gas:

PVnRT
PVnRT

where (in SI metric units):

  • P = the gas absolute pressure, in Pa
  • n = number of moles, in mol
  • V = the gas molar volume, in m3/mol
  • T = the gas absolute temperature, in K
  • R = the universal gas law constant of 8.314472 m3·Pa·mol-1·K-1

or where (in customary USA units):

  • P = the gas absolute pressure, in psia
  • n = number of moles, in lb-mol
  • V = the gas molar volume, in ft3/lb-mol
  • T = the gas absolute temperature, in degrees Rankine (°R)
  • R = the universal gas law constant of 10.7316 ft3·psia·lb-mol-l·°R-1

The mass of a gas will remain constant but the volume and density will change with pressure and temperature (law of conservation of mass).

For this reason, we will use mass instead of volume as a much more relevant term for measuring.

Usually, gases like compressed air or natural gas are measured using standardized molar volume (eg Scf or Nm3).

These terms – at the first glance – look like volumetric terms, which they are not:

Corrected Volume is defined as mass over the density at reference conditions (eg at 0°C and 1013.25mbar; 1.29kg/m3 for air), thus it is a mass term.

A volumetric flow rate with units of CFM or m3 implies that the flow rate was measured at actual conditions (actual pressure, actual temperature).

The distinction between Standardized and Actual is important because it implies that his density changes with pressure and temperature.

This can be seen from taking a look at the ideal gas law. As you may remember, density = mass/volume.

When the ideal gas law is rearranged, the gas density can be seen to be proportional to pressure, and inversely proportional to temperature.

 

Density Formula based on Ideal Gas Law
Density Formula based on Ideal Gas Law

If we take Air for example, Air density at standard conditions is .0752 lb/ft3

Since the air density of an air flow stated at standard conditions (SCFM) is always the same, it is essentially a mass flow rate!

Stating an air flow in units of SCFM makes it easy to compare conditions, and certain calculations simpler.

ρ = m/V → m = ρV →m/t = ρ (V/t)

mass flow rate = density* Volumetric flow rate

In systems with vacuum pumps, blowers, compressors, and heat exchangers, air pressure and temperature are constantly changing, which means the actual volume flow is changing. This makes the specification of volume flow particularly prone to error and misinterpretation. Unless there is a leak, the mass / standard volume flow stays the same, so it is more concise to discuss these systems in terms of mass or standard volume flow. Specify mass or standard volume …be understood!

Standard = 70°F & 14.696 PSIA, Normal = 0°C & 1.013 BarA; these standard conditions are one choice among many standards. For more information see Wikipedia’s page on standard conditions for temperature and pressure.

Usually, Normal Volume is considered as a unit of mass for gases equal to the mass of the reference volume measured at a pressure and temperature of reference conditions.

For example, Ndm3 is a unit of mass for gases equal to the mass of 1 liter (0.035 3147 ft3) at a pressure of 1 atmosphere and at a standard temperature, often 0 °C (32 °F) or 20 °C (68 °F).

To convert from Normal or Standard Conditions to Actual (Operating) Conditions the molar gas volume is needed.

The molar gas volumes can be calculated with an accuracy that is usually sufficient by using the ideal gas law:

 

PVnRT
PV=nRT

 

where (in SI metric units):

  • P = the gas absolute pressure, in Pa
  • n = number of moles, in mol
  • V = the gas molar volume, in m3/mol
  • T = the gas absolute temperature, in K
  • R = the universal gas law constant of 8.314472 m3·Pa·mol-1·K-1

or where (in customary USA units):

  • P = the gas absolute pressure, in psia
  • n = number of moles, in lb-mol
  • V = the gas molar volume, in ft3/lb-mol
  • T = the gas absolute temperature, in degrees Rankine (°R)
  • R = the universal gas law constant of 10.7316 ft3·psia·lb-mol-l·°R-1

Gas volume is directly proportional to temperature and inversely proportional to pressure.

Below are different examples of calculation of molar volume of any ideal gas in several standard temperature and pressure reference conditions:

In SI metric units:

Vm = 8.314472 × 273.15 / 101.325 = 22.414 m3/kmol at 0 °C and 101.325 kPa absolute pressure
Vm = 8.314472 × 273.15 / 100.000 = 22.711 m3/kmol at 0 °C and 100 kPa absolute pressure

In customary USA units:

Vm = 10.7316 × 519.67 / 14.696 = 379.48 ft3/lb-mol at 60 °F and 14.696 psia
Vm = 10.7316 × 519.67 / 14.730 = 378.61 ft3/lb-mol at 60 °F and 14.73 psia

The only reason is to make flowrates under widely differing conditions comparable.

Converting to standard temperature and pressure or normal conditions is just a way of converting volumetric quantities into mass (or molar) based quantities.

Just think of STP or NTP as being another way of expressing mass.

There is no universally accepted “Standard Temperature and Pressure” or “Normal Temperature and Pressure” for gases.

 

4. Standards

There are at least a dozen or more different sets of reference temperature and pressure that are referred to as “standard” or “normal”.

The compressibility of gases means that a cubic meter of gas has different mass whenever pressure and temperature conditions change:

  • A m3 of air at 100 bar (a) and 40 0C has a mass of 112 kg. If the pressure and temperature conditions change, the weight of the air contained in a m3 also changes.
  • A m3 of air at 1.013 bar (a) (equivalent to 1 ata) and 0 0C has a mass of 1.3 kg.
  • One kg of air has a mass of 1 kg.

Therefore, if we express a gas flow in kg / h, the mass of gas to which we refer per unit of time is clearly defined. However, if we use a unit of volume per unit of time (as m3 / h), this information is insufficient to determine the mass of gas per unit of time, and it is essential to clarify the conditions to which the volume is determined.

In this sense, there are two options:

  • Express the volume of gas per unit of time under the actual flow conditions. The difficulty of this measurement is the difficult comparison of flows, even in the same application, since in front of a variation of pressure and / or temperature the flow would vary.
  • Express the volume of gas per unit of time under reference conditions: in this case, we express the volume at arbitrarily set pressure and temperature and used as a reference. This pressure and temperature bear no relation to those of flow. A typical reference condition is 1 absolute atmosphere and 00C, and is known as a normal condition, expressing the flow in normal cubic meters hour (Nm3 / h).
Entity Temp (°C) Temp (°F) Temp (°K) Pressure (kPa) Pressure (psi) Molar Vol [m3] Molar Vol [dm3]
IUPAC (SATP) 25 77 298 100.000 145.038 0,02478 24,777
EPA 25 77 298 101.325 146.959 0,02445 24,453
American Association of Physicists in Medicine 22 72 295 101.325 146.959 0,02421 24,207
AMCA, air density = 0.075 lbm/ft3. This AMCA standard applies only to air.; Compressed Gas Association [CGA] applies to industrial gas use in USA 21 70 294 101300 14.70 0,02413 24,131
EPA, NIST. This is also called NTP, Normal Temperature and Pressure. 20 68 293 101.325 146.959 0,02404 24,043
CAGI 20 68 293 100.000 145.038 0,02436 24,361
ISO 5011 20 68 293 101300 14.69 0,02405 24,049
GOST 2939-63 20 68 293 101330 14.696 0,02404 24,042
SPE, U.S. OSHA, SCAQMD 16 60 289 101330 14.696 0,02371 23,714
EGIA, OPEC, U.S. EIA; U.S. DOT . 16 60 289 101600 14.73 0,02365 23,650
ICAO’s ISA, ISO 13443, EEA, EGIA 15 59 288 101.325 146.959 0,02363 23,633
SPE 15 59 288 100.000 145.038 0,02395 23,946
U.S. Army Standard Metro 15 59 288 99990 14.503 0,02395 23,948
ISO 2314, ISO 3977-2 15 59 288 101330 14.696 0,02363 23,631
Federal Aviation Administration (FAA) 15 59 288 101330 14.70 0,02363 23,631
IUPAC (STP) since 1982 0 32 273 100.000 145.038 0,02270 22,699
NIST, ISO 10780, formerly IUPAC (STP) until 1982 0 32 273 101.325 146.959 0,02240 22,402

The full names of the entities are listed below :

  • IUPAC: International Union of Pure and Applied Chemistry
  • NIST: National Institute of Standards and Technology
  • CODATA: Committee on Data for Science and Technology
  • ISA: ICAO’s International Standard Atmosphere
  • ISO: International Organization for Standardization
  • EEA: European Environment Agency
  • EGIA: Canadian Electricity and Gas Inspection Act
  • U.S. EPA: United States Environmental Protection Agency
  • SATP: Standard Ambient Pressure and Temperature
  • CAGI: Compressed Air and Gas Institute
  • SPE: Society of Petroleum Engineers
  • OSHA: U.S. Occupational Safety and Health Administration
  • SCAQMD: California’s South Coast Air Quality Management District
  • OPEC: Organization of Petroleum Exporting Countries
  • EIA: U.S. Energy Information Administration of the U.S. Department of Energy
  • Std. Metro: U.S. Army’s Standard Metro (used in ballistics)
  • AMCA: Air Movement and Control Association (the AMCA standard applies only to air)

5. Calculators

Visit our New Mass Flow Rate through Piping Calculator!

Visit our New Mass Flow Rate through Piping Calculator!
Visit our New Mass Flow Rate through Piping Calculator!

 

Normal/Standard Flow TO Kg/h and Kg/s CONVERTER

Kg/h TO Normal/Standard Conditions Flow CONVERTER

 

6. References

  • http://en.citizendium.org/wiki/Reference_conditions_of_gas_temperature_and_pressure
  • https://www.mecaflux.com/en/Normaux%20metres%20cubes.htm
  • https://en.wikipedia.org/wiki/Standard_conditions_for_temperature_and_pressure
  • MECAFLUX – https://www.mecaflux.com/en/Normaux%20metres%20cubes.htm
  • https://farnam-custom.com/resources/engineer-talk/scfm-cfm-whats-the-difference/
  • http://xchanger.com/calculators/gas-flow-calculator/

 

Difference between Actual, Standard and Normal Flows
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